Basically, no-one's going to give you better raw materials, they're just going to mess with the dialectic (probably for the worse) by changing whatever the wire is embedded in and then change the cable geometry (which will necessitate going from solid core to stranded cables). While I'm sure things can get better, I suspect it's going to cost you $1000s to find out.
I've also experienced success with VH Audio's .99999 solid core silver in cotton for a DIY interconnect, and Ocellia's silver reference interconnects, which I bought on the recommendation of @charles1dad . In all cases, the silver was better than the copper I had in before.