There have been many opinions on this as well as the dipole vs bipole type of sound. Technically speaking, the 5.1 surrounds are meant to be placed on the left and right walls directly inline where are you sitting. That is how the soundtrack is mixed.
There are the 7.1 "rear surrounds" that are placed on the back wall, but that's an additional channel of processing.
That being said, it's a decision/compromise you will have to make. I would not say that it's necessarily "bad" to place your 5.1 surrounds on the rear wall. It still give you the surround effect, just maybe not quite as accurate as the movie production mixers intended.
There are the 7.1 "rear surrounds" that are placed on the back wall, but that's an additional channel of processing.
That being said, it's a decision/compromise you will have to make. I would not say that it's necessarily "bad" to place your 5.1 surrounds on the rear wall. It still give you the surround effect, just maybe not quite as accurate as the movie production mixers intended.