The REL t5x goes down to 32 hz and my Martin Logans go down to 34 hz. Will I notice the additional 2 hz of bass energy?
The short answer is yes you should, but probably not for the reasons you are thinking. The reason you will notice more extension is because the REL and any other powered sub will have a separate volume control.
Your Martin-Logans like most every other quality speaker manufacturer is more than likely trying to achieve as flat a frequency response curve as they can. The problem is our ears do not perceive frequencies in a linear manner, so at average listening volumes the midrange is going to appear much more present than low bass. Depending on what type of music you listen to, you may actually want to have the low bass several db louder than the mid frequencies to achieve the sound you are looking for. Since all levels are fixed in the ML’s you would need some type of external eq. to make that change which may or may not work for you.
With a separate sub you now have control over the volume relationship between the low bass and mid/hi frequencies. The problem I see in your case with the low roll-off point and the passive radiator of your ML’s, is integrating a sub at a high enough crossover point and volume level with out some type of external crossover will probably be very difficult.
I would recommend something from the JL Audio “e” series and if you are willing to add an external crossover, then pretty much any sub should work.