I have a voltage regulator on my line and notice a fluctuation of up to 10v. It is rare that it will fluctuate more than 1v in a short period of time. For a significant increase in voltage to occur, either an auxiliary power supply we need to go on/off line or a huge number of people would need to do something simultaneously. Not sure this is terribly likely.
Could be break-in, especially if it is going in the same direction (bright to warm or Warm to bright) every time your hear it change. Do you notice a difference if the system is on for a while prior to listening or if your turn the system on fresh?
Another obvious spot to look is the weak link in your audio chain which is that Mac Mini. I talk to lots of people and more often than not, if something bizarre is happening in their system, a Mac Mini is involved. Does anything else run on that Mac Mini? If something else is taxing the processor, that could be your issue. It would also explain why you might hear a change mid-song.