IMO, you will not be satisfied with super-cheap XLR interconnects in a high fidelity sound system. At least not if you compare them to much higher grade gear made by Audioquest, Pangea, or a great many others specializing in audio playback. You can easily get much higher quality without breaking the bank. For example,
AudioQuest Red River XLR to XLR Analog Audio Interconnect Cables - 3.28' (1m) - Pair is a good high-end entry level choice.
Now, whether XLR is "better" than RCA, there are no absolute rules. XLR (balanced) does have certain advantages such as higher gain, as well as theoretical advantages. I am running fully balanced from source components to Freya+ to power amps, but not everyone does this and it is hardly necessary. Decent quality RCA cables are generally less costly than XLR, for obvious reasons.