Tonality near a limit, ie, pure red, blue, or green, or CMYK.
Anything that is close to the limit of being a pure tone, or, conversely... whitish with a hair of the given pure tone.
Those are the hardest for any paint matching/measuring system to match up to.
You are dealing with not a black but a close analog. Which means it might not come out as perfect as you want or expect it to.
~~~~~~~~~~~~~
Insert Long story about bit depth and fineness at limits (either end, it depends), semiconductor sensitivities, software/hardware design by people who don’t understand the sciences/physics involved, and the extreme sensitivity in the human eye when comparing two things that are next to each other.