I was taught by the various audio magazines that 33rpm LP was the best available format for sonics, and yet when a friend bought round his 45rpm 12 inch single of Duran Duran's 'The Wild Boys' the dynamics were something my Linn/Naim system had never before conveyed.
In fact I can't recall hearing a poor sounding 12 inch 45rpm single. Therefore my vote goes to the 45rpm.