More than anything else a good active preamp will provide a more 3D soundstage.Of course they have to synergise with the power amp to do that but when you get the combination right it can make the difference between a good sound and a really great one.It is simply sounds more involving because it is revealing more of the stereo effect that is encoded in the recording.It is higher resolution.
Some active valve preamps will add tonal colour and some are tonally neutral.Some SS active preamps add tonal colour too.It is just a matter of finding the one you prefer.
I have found the Supratek 6SN7 based preamps to be tonally neutral.Very clear and open and 3D but neutral.I have heard SS preamps that sound very similar but they are very high end Swiss designs that cost 4-5 times as much.