I have never used XLR cables. But in another thread I gave my recollection of what the person I consider the subject matter expert had to say. Quoting myself:
According to Ralph (Atmasphere), if both components use true balanced architecture, there is minimal benefit in using uber expensive balanced interconnects. Ralph, if I have misinterpreted the above feel free to correct me.
And in the same thread @gdnrbob added:
Though I might have read it wrong, I believe Ralph's (Atmasphere) belief in using equipment that adheres to the AES standard is that it minimizes cable artifacts (sound differences). Given that recording studios use such equipment, and their cables can stretch of long distances, it makes sense to use it.
So, if your equipment follows the AES standard, then XLR cables will/should not 'color' the sound as much as RCA cables. (And, from my limited experience moving between Mogami and AQ, there was very little difference in sound quality).