I think you just need to run the cable from the Powernode's Sub Out to the LFE input on the sub (the white/left input). There is also a switch on the sub that you set to LFE.
In the BluOS app, turn on the Sub in the Audio settings. The sub output is always on, but turning on the Sub button will engage the crossover settings. Play around with different settings (80Hz is a pretty high crossover point). As an aside, in the system where I have a Powernode, I actually run the speakers full range (Sub switched off, but still sending signal to the sub). I think it sounds better in that room, even though it doesn't measure the flattest.