"Ambient" is very similar to what used to be known as "space music". Check out the early to mid 70's Tangerine Dream, Ash Ra Temple, Klaus Schulze. Rayd
I like Aphex Twin's "Selected Amibient Works VII'. Volume one, though, is more techno, more boring. Orbital is good, so is Eno. Slowdrive is something to look at. They have a song on the 'Doom Generation' sndtrk, 'blue skied an' clear' that's pretty good with a gigantic, enveloping sound.
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