PM uses the output device selected in the Audio Midi Setup program found in your Applications-Utilities folder. If nothing else is attached it will use the built in output which would be the optical or analog jack on the computer. If you have any USB or Firewire audio devices it will allow you to select those as the output device.
If you select hog mode in the PM preferences - advanced audio setup then you set the Audio Midi to built in output and select your device from within those advanced settings.
PM doesn't use any part of iTunes to actually play the file so it seams impossible it could allow iTunes to control where the stream goes. Airport Extremes are limited to 16/44.1K anyway so you could not use any of the upsampling features of PM or play higher resolution files.
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If you select hog mode in the PM preferences - advanced audio setup then you set the Audio Midi to built in output and select your device from within those advanced settings.
PM doesn't use any part of iTunes to actually play the file so it seams impossible it could allow iTunes to control where the stream goes. Airport Extremes are limited to 16/44.1K anyway so you could not use any of the upsampling features of PM or play higher resolution files.
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