Not to stick my neck out too far, but I think a large part of the reason is inductance, specifically inductance at frequency. I know XLO, and probably others, feel that DC resistance isn't the overarching factor that it might seem based on the 'numbers game', since audio deals with AC. If I speculate that some of these precious metals feature a higher increase in self-inductance with frequency compared to copper, that might explain why some feel that gold and palladium sound more 'natural', perhaps because these metals slightly reduce harshness and glare.
Just a guess.
Don't kill the messenger.
Just a guess.
Don't kill the messenger.