Rostropovich on Teldec with a chamber ensemble (I'm too lazy to go to my basement and tell you the exact details) playing a Vivaldi piece. Always start with that. A couple of bars into it the music drops a couple of octaves, and that moment is when amplifiers get their soul exposed for the world to see. Dynamics, microdynamics, ability to raise current as speaker impedance drops, attack and decay, all tested at once. Also Roger Waters' Amused to Death for soundstaging, Vienna Teng for vocal naturality, Massive Attack or Thievery Corporation for bass, Nils Peter Molvaer for range and detail, etc.