I can't tell from your comments exactly how much actual speaker/sitting positioning work you have already done, or how you did it, so it is really hard to comment on what you should do next.
BUT, IMHO, you really can't get your sound to 'improve' until you can describe specifically what it is that you expect to improve by making any changes or use of 'room treatments'.
FWIW, it strikes me from your comment 'it sounds good to me' that you really haven't a focus on exactly what to expect, just that you think by adding something it might get better, when actually it not only might not, it might sound worse.
Based on that assumption, I would suggest that you save your money for a while and try to improve the sounds in your room (assuming you are not restricted by WAF) simply by carefully tweeking placement/toe/listening chair positiong until your set up produces tonal smoothness from bass thru highs (you can use a SPL meter and a disc with test tones) and clarity of tone, a set up which produces this clarity in the context of a soundstage which is wide and deep (and if possible, but it is more equipment dependent, high).
Room treatments are good when you have identified specific problems in identified frequencies and select the treatments that are designed to do it. There is no 'one size fits all' solutions, and some things are unobtainable at any realistic price or visual acceptance to many.
FWIW, I've been able to set up a modest sized room with fairly flat/smooth frequency response +/- about 3db except for a 5db boost at 32hz (not tameable) and a 40/50 hz 5db suckout (room dimension created and not tameable either) without using any acoustic materiels other than normal domestic furnishings. It only took a couple of years to do it all. Lots of small changes and patient listening to speaker/listening seat tweaking. :-)
If you want some down and dirty recommendations, I would suggest that you post your rooms dimensions, identify present locations of speakers and listening chair, along with a description of and location of room openings (windows and doors), and stuff placed on/near walls.
Also a description of your equipment, especially your speakers, and if possible what you would like to improve, sonically.
Fundmentally I agree with Sbank - I would only like to reinforce the fact that speaker/room set up, assuming you have already done some of the preliminary work, and if you have high expectations, is not a short term project with quick fixes. It is a slow methodical process with a lot of small changes and patient listening.
Hope that helps a bit.........