Of course 7N copper exists. It is even a subject of international conferences like this one:
http://jp4.journaldephysique.org/index.php?option=com_article&access=standard&Itemid=129&url=/articles/jp4/abs/1995/07/jp4199505C747/jp4199505C747.html
In addition to limits of purity Continuous Casting process produces extremely long crystals (many feet long) by very slow cooling of the copper in hot forms (to prevent crystallization). In comparison common oxygen free copper has thousands of crystals per foot. Impurities resides between crystals. Copper Oxide is a semiconductor.
http://jp4.journaldephysique.org/index.php?option=com_article&access=standard&Itemid=129&url=/articles/jp4/abs/1995/07/jp4199505C747/jp4199505C747.html
In addition to limits of purity Continuous Casting process produces extremely long crystals (many feet long) by very slow cooling of the copper in hot forms (to prevent crystallization). In comparison common oxygen free copper has thousands of crystals per foot. Impurities resides between crystals. Copper Oxide is a semiconductor.