If you stay PC (noticed, like me, that you ae thinking of making the switch to a Mac, assuming all is simpler and purer there) I'd give a listen to this:
1)EAC to FLAC (lossless open-code that has a Mac version too)
2)FLAC playback through Foobar 0.8.3 (older version, still sounds best), with the SSRC 24/96 upsampler plugin in Foobar
3) Out to your great PS Audio DAC III (USB doesn't like 24/96, so I'd try coax out w/resampling vs no resampling-with-USB; one choice will be better)
It's what I do (non-USB dac currently), but I'm gonna demo the Wavelength USB Dacs, and Gordon says I should go Mac. My own problem is when i ripped in FLAC I ripped to large album files and use CUE sheets (associated file that has all the tags, etc. and Mac doesn't support that mess). If I go MAc I'll use itunesencoder.exe and batch convert all to Apple Lossless and use iTunes on Mac.