I actually missed that last sentence in the OP. That is an interesting way to do it and he might get a decent result.
AirPort Express I think used to top out at CD quality.
AirPlay isn’t that bad, pretty close to a standard redbook CD. It’s definitely an improvement over Bluetooth although I haven’t heard the latest Bluetooth codec. I use streaming primarily to investigate material that I don’t own and then if I really like it I buy a CD or download. With some older recordings, especially stuff that appeared on budget Classical labels such as Vox, there really isn’t any difference between the CD and AirPlay