Sub woofers crossed over at 80hz, assuming that the cross over slope is at 12bd per octave will still have significant output at 160hz and some at 320 hz the result of which will be an enriched sound from the left speaker in that range and will skew the balance a bit. IF, your problem is NOT related to the left speakers placement near the corner then floor standers might help because the woofer on the left will be operating 3db lower than the sub to get a balanced response with the other floorstander.
As mentioned, for reference only, move your sub to the right side and see what happens to the balance. If you have a SPL meter and a test disc it will be much easier for you and you can run the system in mono on each side to cee the difference in db's between having the woofer on the left or the right, IF there is one.
I'll mention my set up experience experience with floorstanders only to give you an idea of the things you can effect with a little time, an open mind (sonically speaking) and without having to buy any audio acoustic materiels (as opposed to domestically approved stuff). I have the same issue in my room. Wall on the left side, big double door opening on the right side at the speaker location. Room is a bit bigger than yours. Two things have helped me get an excellent sense of width, depth, and balance. The speaker on the 'wall' side is aprox 30" from the side wall and 65" from the back wall. The speaker on the right side is about 12 inches (measured at the tweeter) from the opening where the wall would be, and also 65" from the back wall. The speakers are about 9' apart and I sit about 11 ft from the plane of the speakers. I toe the speakers in so that their axis' cross in front of my listening chair. This minimizes reflections from the left wall, and I believe changes the reflection pattern from the ceiling and helps decouple it from the direct signal. The result is flat +/- 3db except for a small node at 32hz of about 5db. This location took a lot of work and time to find, but it was worth it. BTW, I have pocket doors in the opening and open v closed had little effect on my results.
FWIW. No charge! :-)