Yes, RMS = root mean square. As you probably realize, the signal provided to a speaker consists of various frequency components each of which is AC (alternating current). Amplifier power capability is defined based on the simplified assumption that the signal consists of a pure sine wave at a single frequency, with that single frequency being anywhere within some range of frequencies, such as 20 Hz to 20 KHz. The RMS value of a sine wave equals its peak (maximum) instantaneous value divided by the square root of 2, or approximately 0.707 x the peak value.
In audio voltages and currents are usually defined on an RMS basis, in part because the amount of power supplied to a resistive load that can be calculated based on RMS voltage and current numbers (even for waveforms that are not sine waves) equals the amount of power that would result from a DC (direct current) voltage and current having the same values, that amount of power in turn being proportional to the amount of heat that is produced when supplied to ("dissipated in") a resistive load.
By the way, one thing that often causes confusion in this context is that the word "peak" can be used to mean two different things. It can refer to the peak (maximum) value of a sine wave or other signal at any instant of time during each of its cycles (corresponding for a sine wave to the RMS value divided by 0.707), or it can refer to the peak (maximum) RMS value that can be reached by that sine wave or other signal during normal (or other) operating conditions.
Kudos for your interest in these matters. Regards,
-- Al