Little theory.
A capacitor is 2 conductive plates with an insulator. You can make one out of aluminum foil and wax paper, but it will be very very low Farads. I’ve done it. Tiny capacitance. Like, nano-Farads.
Commercial caps use insulators with a thickness measured in micrometers.
To increase the voltage rating of a cap you must make the insulator thicker, which then makes the need for more conductive material to compensate for the increased distance. This need for a thicker insulator is the driving factor on the rest of the design. This is true for ALL capacitors. Look at a 10uF electrolytic at different voltages. The 5V is tiny compared to the 60V variety.
Some uber-expensive caps like Mundorf Supreme’s are made as 2 caps in series in a single package. This cuts the effective uF by four, while doubling the voltage rating. You could do this yourself. With a pair of 20uF/100V caps:
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You would have the equivalent of a 10uF/200V cap, even though you used 40uF worth of capacitors.
This is why these boutique caps are so much larger physically and in some ways justifies the price. The material cost just went up by 4!
Best,
E