I have NOS Mullards ECC 82’s , sounds like somebody threw a blanket over my system . Kinda like pushing the Dolby button on a cassette player .
As always, YMMV.
Regarding Mullard and other NOS brands, if they are noise-tested they should sound good for many hours. There are several types of Mullards; longplates, shortplates, ladder plates, with square getter or with halo getter. ECC82 labelled "Made in Great Britain" are of the highest build-quality.
There is a "house sound" to these tubes, warmth with a relaxed top-end (since they are British they should be called valves).
1950’s ECC82 longplate square getters present open and warm sonics with rich textures; I own several pairs. The CV4003 is a military-spec boxplate with a wide soundstage, and to my ears, sound more "lively," whereas the short plate sounds more "closed-in."
Philips tubes made in the UK factory will have the same sonic signature as Mullard. Phillips Holland was the parent company of Mullard and Amperex.