I've always been curious about the Sierra's -- right up to the point of buying them. I bought Salk SS6m's. I love them.
One consideration might be the speaker-room synergy or lack thereof. One speaker is a tower and the other is stand mount, no? Perhaps there's something nimble and direct about the Ascend which the Salks, in your space don't have? My Salks are standmounts, and they beat out a variety of towers.
If I were you, I'd be very sure the Salks were no longer your cup of tea. I think Jim makes heirloom, high quality stuff and I'd expect it would take a long time to tire of them. Still, never know. Sometimes a divorce is just what the doctor (or lawyer) ordered.