What value is important the uf or the vdc
The critical value is uF, micro-Farads, the unit of capacitance. VDC is voltage, which matters only in that you do not want to use a low voltage cap with high voltage as it can destroy the cap. Crossovers are in the single digits to tens of volts, not hundreds, so this number 630VDC is irrelevant. You just don't want one that is too low.
Capacitors in crossovers are sometimes called filter caps because that is what they do, filter lower frequencies. The greater the capacitance the more energy the cap stores. Because of this, if you change the value from say 100uF to 150uF this will shift the frequency and this will cause the speaker to sound different.
All caps and resistors have a tolerance, typically of a few percent, often printed on the part along with the value. So if your cap is 100uF +/- 5% it can be 95 to 105uF. If the manufacturer specs this cap that alone should be enough to tell you one or two uF one way or the other is not critical. If you really want to know you can buy a LCR meter and measure actual capacitance and inductance yourself.
The idea someone had that the only thing that matters is the measured value and gives as his "reason" because, physics, is patently false. The better caps do indeed sound better even though they measure the same. And you want to know why? PHYSICS!
What is actually happening inside a cap is electron charges are constantly shifting one way and another, in and out, according to the music signal. When we measure all we get is a static, fixed state number. There is nothing in it having anything to do with how fast and smooth these charges shift back and forth. Which with music is EVERYTHING! That is why some of these expensive caps use such an elaborate manufacturing process, to ensure extreme consistency and sensitivity down to the electron level.
It ain’t cheap. It ain’t easy. And it can’t be measured by no meter. Thus the link to the cap comparison page above.