I listened to some solo violin and cello, some folky vocals, some Led Zepp just because :0)
maybe music where instruments are easily located ect
I think you are on the right track listening to solo acoustic instruments. I would add some chamber music to your playlist, so you can get a good picture of how they are reproducing instruments in relation to each other, in an actual acoustic space.
When I am first setting up a system, I try to avoid recordings with a lot of studio production methods, since they tend to disguise how an instrument sounds playing without effects, in a real acoustic space.
This will also get you a natural sounding soundstage and image, without studio panning, digital delays, phase changes, etc.