The lps on router was relatively large change IME. I don't understand why you're using usb when you have Synology NAS. NAS is network only connection, likely superior to any usb storage. I use AQ Vodka ethernet cable with my Synology NAS, better than any usb storage I've tried. Don't know why Meitner auto switches to network vs usb, other MA3 owners will have to chime in here.
When you do comparison, direct vs. mini, report back, I for one would be interested. You could also try something like Network Acoustics Eno, Muon or Uptone Etherregen between mini (or router whether you go with direct route to Meitner or keep in mini server chain-in this case between router and mini) and Meitner. Mini or any server is generator of noise in streaming chain, lowering noise floor prior to streamers will result in greater resolution, likely more natural sound.