You can find great tube amps throughout the time they have been made. There haven’t been any technological breakthroughs in recent decades that render older models mere outmoded. One of the best I’ve ever heard is the Western Electric 59A, which is from the early 1930’s. I also like Western Electric 124 and 133 amps.
I have heard a few good OTL amps from the 1990’s to current times and these might be considered more “recent” in design than most tube amps. The quasi-OTL amps, like Berning’s ZOTL amps, represent a sort of modern innovation, but, I personally don’t much care for the sound of the amps I’ve heard.
Most of the parts in tube amps have not been improved much in a very long time. The best output transformers from the past remain highly sought after because they sound better than most currently manufactured ones (e.g., Chicago, Accrosound, Western Electric). The same with tubes themselves—many older tubes sound better than current versions. Perhaps some newer parts, like teflon caps, are an improvement in certain applications, but, in many of the amps I really like, old parts, like some paper-in-oil caps sound very good. Some current manufacturers make great new parts, like Audio Note, but they charge a small fortune for them.