I recommend buying s Sound Pressure Meter
Set it up on a tripod, ear level, listening position.
Then play test tones, measuring spl of each tone. Find best arrangement.
Generally, tilt back so tweeters are aimed at seated ear level. Then toe-in so speakers are facing you directly. Both alter the angles of reflection regarding floor, ceiling, side walls.
Alternate toe-in for listening with a friend. Aim right speaker at left chair; right speaker aimed at right seat. This gives fairly good imaging of both sides and center. Closer to the speaker your side's volume, but more direct radiation/volume from other side, works!