You guys are funny... I have had many a DAC hooked up to my PC and they ALL made substantial differences. So PCs are not limited just like many claim an automobile is so limited and no human can tell the difference between DSD and an MP3. Such rubbish being spread about...
I currently have an Ayre Codex and a PS Audio Steller DAC/Pre. I've had Schitt Modi MB and a Topping D90SE and those both sucked in comparison. I want to try a Benchmark DAC3 HGC eventually. Heck, I had some pretty crappy speakers from Logitech at first. Then went to Audio Engine, Focal and now a pair of Ascend Acoustics Sierra 2SEs. It all made a difference. I master my vinyl rips on my PC, which is why I care about the SQ so much.