alignment filter is the crossover network between woofer, midrange and tweeter. you would need 3 amps to run fully active and a good working knowledge of appropriate crossover frequencies, slopes and level matching the drivers as well as if there was an impedance flattener, notch filter, baffle step compensation and roll off filter. not for the uninitiated.
run the amps as you have planned using a splitter off one set of outputs. you should enjoy the difference assuming the adcoms are up to snuff.