After I put up my first configuration of treatments (absorption and diffusion) I would run my RTA with Pink noise and walk around the room. As I heard the sound change, I would point the microphone in various directions to see which frequencies were changing in relation to what I was hearing. When I identified problem areas, I could decide what treatment was needed based on that, and assess the changes. Generally, areas where highs were peaking got more absorption, boomy areas get more diffusion. Sometimes it's some of both.
Trust your ears.