Hmmm...
I recently bought one Python cable, TWO King Cobras, one Black Mamba, and one Taipan.
I can definitely NOT confirm that the Python matches the King Cobra. However, I DID buy the King Cobra on Audiogon. I can tell ya, I put it into a friend's system, composed of Mirage 490 speakers (1990 vintage), Arcam Alpha 7, JVC XLZ1010 CD player, and Transparent Music Wave speaker cable.
The sound was glorious for such an inexpensive system. The Cobra will give you more than additional ambience (compares with the Python); it will give you a small sense of "here-and-now," even in an inexpensive system.
I replaced the KC with the Black Mamba and the sound was good, but not up to King Cobra standards. Even the Python, good as it is, is NOT in the same league. In fact, I would go so far as to say, buy a King Cobra, and consider it a MAJOR component, and take it with you to test your other purchases.
In the past, I would NOT have ascribed power cords the power (no pun intended) they can allow a system to advance, but that was then. And the Shunyatas are absolute killer components. No need to compare them to anything; they stand out on their own.