It's a combination of your speaker location and your listening position in the BIG problem called, your ROOM. As you mentioned, when you are against the wall (at a boundry) the problem goes away. So if possible, consider re-arranging your room so your listening position is AT the rear wall.
If rearrangement is possible, also consider placing the speakers across the 24' wall. If that is doable, start with bringing each speaker 6' from the side wall to the center of the driver. That will give you 12' between the speakers.
Locate them mid-way into the room and your listening location against the rear wall. Be sure your ears are ABOVE the back of the chair/sofa you are using.
Start there and move your head forward and backward and notice the difference in the soundstage and imaging. When you find the point that sounds best, place your seat so that you are AT that point when you sit naturally.
Also, play with the toe-in on the speakers. A $20 laser level is good for proper alignment there.
Do this with the Dakron stuffing removed from the Cains.
You'll know it when you find the magic spot!
There's more you can do with cheap tweaks to the room, but this will be a good start to "work with what you've got".
Good luck and let's hear back from you with the results?