The answer to your original question is NO. Adding a subwoofer won't change the speakers sensitivity. Removing low bass frequencies will lessen amplifier clipping (on most types of music), but it won't effect the maximum volume level attainable by the amp/speaker combo. So the system could sound cleaner, less distortion, but it won't go any louder.
Calculating max SPLs is fairly simple. Matching a speaker's impedance to an appropriate amp is more complicated. You need to be more specific about the amps you're considering to get more detailed and better replies.
Calculating max SPLs is fairly simple. Matching a speaker's impedance to an appropriate amp is more complicated. You need to be more specific about the amps you're considering to get more detailed and better replies.