Arm,
I stipulated that it would be Very unusual for this to actually happen. Fact is, Silicon O-rings have a silicon oil binder in them. Period. If you saw evidence of this on a preamp, it would probably be WAY too hot. Output tubes? I don't know how hot they get. You are more likely to see such oils on output tubes, but still and all, since I've never seen it noted, I'll have to call it a real long shot.
If I owned a tube amp......and felt the need for tube damping, I'd make sure I bought either Kalrez or Vacuum baked Silicon. Your gonna have to trust me on this one. We chased a contamination problem for months in a 'wafer fab'. A place making 'chips'. We knew everything but the cause. One engineer suggested the silicon O-rings as the cause. We baked some ourselves and collected a couple teaspoons of oil from the catch cup we fabricated. In all fairness, we baked maybe enough silicon rings for 100 tube dampers. But, when we used 'em, the problem went away like we flipped a switch.
In short, the oil is real, You will only see it if something is seriously wrong and WAY over heats. I may have OCD!