You may need attentuators on one of the amps. Far less than a 1 db imbalance can be enough to skew the tonal response. You could use a single amp with jumpers on the speakers as a reference point for the "normal" tonal balance. On some speakers, the gauge of the jumpers relative to the main speaker cable may also effect the tonal balance.
If there is an amp level mismatch, you also might experiment with the mixed preamp outputs. Connect the XLRs to the amp with less gain.
With attentuators, you can dial it in. Depending on the crossover frequency, attentuators on the bass amp might not effect the perceived signal purity too much. On the treble amp, YMMV.
Even when the tonal balance is correct, a big disparity in dynamic range or slew rate between the amps may make for a disjointed sound. Again, using a single amp with jumpers will provide a point of reference.
If there is an amp level mismatch, you also might experiment with the mixed preamp outputs. Connect the XLRs to the amp with less gain.
With attentuators, you can dial it in. Depending on the crossover frequency, attentuators on the bass amp might not effect the perceived signal purity too much. On the treble amp, YMMV.
Even when the tonal balance is correct, a big disparity in dynamic range or slew rate between the amps may make for a disjointed sound. Again, using a single amp with jumpers will provide a point of reference.