My additions to a lot of good folks already mentioned:
Rebecca Gates, 'Ruby Series' more of an extended EP (7 songs) but well worth it
The Innocence Mission, 'glow'
Everything But the Girl, 'Walking Wounded,' electronic, but Tracey Thorn's voice is amazing
And though this isn't all female vocals, the soundtrack to the movie, 'First Love, Last Rites' has great collaborations between Shudder to Think and Liz Phair, Nina Persson (Cardigans), and Angela McCluskey (Wild Colonials).
Rebecca Gates, 'Ruby Series' more of an extended EP (7 songs) but well worth it
The Innocence Mission, 'glow'
Everything But the Girl, 'Walking Wounded,' electronic, but Tracey Thorn's voice is amazing
And though this isn't all female vocals, the soundtrack to the movie, 'First Love, Last Rites' has great collaborations between Shudder to Think and Liz Phair, Nina Persson (Cardigans), and Angela McCluskey (Wild Colonials).