I work for a utility and 4 to 5 pm is near the peak and probably still increasing. Now some solar will come off if you have solar. Solar and wind are the worst power--not synchronized to the grid and have to be managed by the system. I have an oscilloscope on my power and total harmonic distortion does not change much with the clock. the thought that your system sounds better at night because the power is cleaner is an old wives tale. It sounds better because less ambient noise, relaxed listener, and pehaps a glass of wine.
I would not expect bad power to make your system sound harsh since that implies a change in bass/treble balance. It would more affect transparency, detail, accuracy and soundstage.
As for fixing summer bad power, the only way to do it is regenerative. "conditioners" that just try to filter noise are either useless or worse.
JErry