When I spoke with Roger Modjeski (of Music Reference) about mating subs with the old QUAD ESL loudspeaker---of which he was a huge fan and owner, he recommended employing a crossover frequency of 100Hz, with 4th-order filters in both directions (high pass and low). He maintained that the bass panels of the ESL had a rather pronounced resonance in the 50Hz-100Hz frequency band, and benefited from not allowing the panels to reproduce those frequencies.
The subject of whether or not to use a high pass filter with the main speakers is a matter of some disagreement. Making a seamless transition from speakers to subs is not easy, but having as good a set of subs as possible is of course the place to start, whatever crossover filter characteristics one prefers.
It is my opinion that relieving the loudspeakers the duty of reproducing very low frequencies can greatly benefit the loudspeaker’s reproduction of the higher frequencies the woofer must also reproduce (commonly into the midrange). Employing a crossover frequency of 100Hz with 4th-order filters is a good general recommendation. Finding the best room locations is the next order of business.
Place them where they best address the room’s high and low pressure zones, where bass frequencies either disappear into black holes or "ring" far past the point where the signal has ended, the result of the room’s dimensions creating those zones, referred to as "eigenmodes". Tho location of the "modes" of any given room can be found by entering the room’s dimensions into one of the mode calculators findable via a Google search. If at all possible, do NOT place your subs in those locations.