We have tried both PCs and Macs, during the development of our latest product. All the Macs were spot on. The PCs went all over the map. Everything from "This sounds great" to "Are you sure that this thing isn't broken?" Same unit, same sound system, highly variable results when using a PC.
I think sound quality is not an issue. Mac or PC can be equal there. IMMHO i thinks it's all about skills with a PC. If you want to take the time to learn whats required you can save your self a boat load of money. Mac's are "Plug & Play" and you will pay for it too.
I went with a Mac Mini, the cheapest model and used an old monitor and keyboard. Plugged in my old windows formatted my Seagate external drive and it was up and running in 10 minutes.
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