the cap would of course go in series w/ the high freq amp, while the low freq amp (the sub) you could simply rely on its own internal crossover to filter out higher freq infoFor hi pass, cap in series, correct.
Matching the two xovers, however, may take some experimentation: if the sub's xover is not 1st order (6dB/octave) electrical -- which it probably isn't -- you may just get away with playing w/ the low pass frequency. This worked for me once, where the powered woofers part of the speaker system was detachable from the rest of the speaker; the cut off for the woof (12dB/electrical) was set ~1 octave lower than the main; then we used placement of powered woofs to compensate for the phase differences between the two.