Yes if the copper chloride is perfectly dry it is a yellow-brown color but in the presence of moisture it easily forms the dihydrate which is a green color. This is what you typically see due to moisture in the atmosphere. Copper chloride is always hydrated to some extent on exposure to atmosphere and forms green crystals.
Unstabilized PVC undergoes dehydrohalogenation very readily on exposure to UV or heat. The dehydrohalogenation process releases HCl. I studied this extensively using Photoelectron Spectroscopy as I stated before. The added stabilizers slow down the process but do not completely eliminate it.
The dehydrohalogenation processs takes place at the surface initially (the upper 5 to 10 nanometers) and slowly works its way into the bulk. This initial process which occurs within minutes of UV exposure can only be detected with a surface analysis technique like Photoelectron Spectroscopy or Static Secondary Ion Mass Spectrometry.
As far as heat, the surface dehydrohalogenation begins to occur at temperatures of 70 to 90 degrees C (160 to 190 F).
The combination of UV and elevated temperatures (greater than 100 degrees F) speeds up the process significantly.
Unstabilized PVC undergoes dehydrohalogenation very readily on exposure to UV or heat. The dehydrohalogenation process releases HCl. I studied this extensively using Photoelectron Spectroscopy as I stated before. The added stabilizers slow down the process but do not completely eliminate it.
The dehydrohalogenation processs takes place at the surface initially (the upper 5 to 10 nanometers) and slowly works its way into the bulk. This initial process which occurs within minutes of UV exposure can only be detected with a surface analysis technique like Photoelectron Spectroscopy or Static Secondary Ion Mass Spectrometry.
As far as heat, the surface dehydrohalogenation begins to occur at temperatures of 70 to 90 degrees C (160 to 190 F).
The combination of UV and elevated temperatures (greater than 100 degrees F) speeds up the process significantly.