I'll give you guys a mystery of my own. I got into upgrading speakers for a little while and the results were fun and educational.
I used a DATS V2 to measure replacement parts. I believe Focals use Solen as their OEM and IMHO it shows. I really prefer the sound of the almost as inexpensive Mundorf MKPs instead. Anyway, I replaced the tweeter caps after measuring the original and new caps for capacitance and equivalent series resistance (ESR). Both were very very similar.
For about 4 days after replacement I kept hearing weird surround sound effects. I would hear sounds from the recording appear to happen below and behind me. Later on this cleared up and never happened again. The resulting sound was less harsh and more mellow than the original caps.
The weird sound effects I have always chalked up to head related transfer function (HRTF) effects. The idea that the right comb filtering can make us hear things happen in 3D space.
HRTF effects are complicated. If I wanted to measure or prove/disprove this was happening I'd need to have recorded the sound and compared the frequency response and phase responses of the before and after. If that measured the same I'd chalk it up to my hearing, but to this day I think HRTF would explain what I heard and capacitor break-in behavior a lot more than uF and ESR.